For the purpose of improving the reactivity, metal- azole complexes were synthesized and their
properties were investigated. 1H - Tetrazole and 1H - 1,2,4 - triazole were used for the lingands which
contain nitrogen atoms and can coordinate to metals. Copper was selected as the central metal in
anticipation of the catalytic effect. For the counter anion, nitrate was used. The 1H - tetrazole
complex was obtained as the salt, [Cu(CHN4)2]H20. The 1H - 1,2,4 - triazole was obtained
as [Cu(C2H3N3)2](NO3)2.
From the results of the sensitivity tests, the complexes were insensitive to impact and friction.
However, they are sensitive to static eletctricity. Compared with pure azoles, the coordination
changed the thermal stability and reactivity during the DSC meassurement. The complexes generated
oxidative gases during the flash pyrolysis / FT - IR measurement while pure azole generated
HCN. NH3 and hydrocarbons. From the deflagration test, it was found that these complexes could
produce a large amount of gaseous species and the rate of pressure generation was high.
反応性の向上を目的として金属 - アゾール類錯体を合成し, その性質を調べた｡ 配位子として, 金属に配位可能な窒素原子を含む1H - テトラゾールと1H - 1,2,4 - テトラゾールを用いた｡ 中心金属には, 触媒効果が期待される銅を選んだ｡ また, 対イオンには硝酸イオンを用いた｡ 1H - テトラゾールは合成の結果塩である[Cu(CHN4)2]H20が得られた｡ また, 1H - 1,2,4 - テトラゾールからは[Cu(C2H3N3)2](NO3)2が得られた｡
感度試験の結果, 錯体は打撃感度, 摩擦感度は鈍感であったが, 静電気感度は鋭感であった｡ また, アゾール類と比較してDSC測定では錯体化によって熱安定性と反応性が変化することがわかった｡ 高速熱分解 / FT - IR測定では, 錯体が酸化されたガスを放出することがわかった｡ 爆燃性試験からはこれらの錯体によって高い圧力と圧力発生速度が発生することがわかった。